西班牙专利ES2555542A1 Embedded sensor for continuous measurement of mechanical resistances in structures of cementitious m

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专利摘要:
Sensor for the continuous measurement of mechanical resistances in a cementitious material structure. Another object of the invention refers to two measurement systems that use said sensor: a continuous measurement system based on an electromagnetic induction effect, and another continuous measurement system based on a magneto-inductance effect, as well as the measurement method of each system and a method of manufacturing said sensor the sensor is embedded directly, as a simple addition, in a structure of cement material, preferably concrete, so that it allows to measure the state of mechanical stress/internal deformation of said structure of material cementitiously and without affecting its structure or its state of tension. The sensor comprises a block of cementitious material in which a magnetic microwire is embedded wherein said magnetic microwire comprises a ferromagnetic core and an insulating coating of glass. (Machine-translation by Google Translate, not legally binding)
公开号:ES2555542A1
申请号:ES201430787
申请日:2014-05-27
公开日:2016-01-04
发明作者:Jesús OLIVERA CABO；José Javier Anaya Velayos；Margarita GONZÁLEZ HERNÁNDEZ；Sofia APARICIO SECANELLAS；Ratislav VARGA；Marian ROVNAK；José Vicente FUENTES RAMÍREZ
申请人:Asociacion De Investigacion De Industrias de la Construccion - Aidico - Instituto Tecnologico de la Construccion；Pavol Jozef Safarik University In Kosice；Technical University Of Kosice；Asoc De Investig De Ind de la Constr - Aidico - Inst Tecnologico de la Constr；Consejo Superior de Investigaciones Cientificas CSIC；Pavol Jozef Safarik Univ In Kosice；Tech Univ Of Kosice；
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专利说明:

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different magnitudes, and its simple measurement and manufacturing processes.
One of the technological applications of these magnetic microwires is based on the effect of Magnetic Bistability and can be used in numerous applications, mainly using very sharp voltage peaks induced in small windings as a consequence of the propagation process of the magnetization inversion. , as will be explained in detail later. These magnetic pulses have been used in many different applications, such as pulse generators, position and displacement sensors, magnetic field sensors, magnetoelastic sensors, speed counters and goniometers, etc.
Therefore, the present invention provides a sensor that has the following advantages:
- allows to measure the mechanical resistance of any structure made of cementitious material continuously,
- allows to measure without contact the internal mechanical stresses of the structure of cementitious material,
- it is embedded directly in the structure of cementitious material to be studied without affecting its structure or the state of tension,
- thermal treatments are applied that, on the one hand, allow to improve the stability of the sensor over time, and on the other, adapt the sensitivity of the sensor to the mechanical stresses applied to the range of mechanical stresses applied in which the sensor will work.
DESCRIPTION OF THE INVENTION
The present invention relates to a sensor embedded for the continuous measurement of mechanical resistance in cementitious material structures (preferably the structure of cementitious material is concrete), such that it comprises: at least one magnetic micro wire selected between amorphous and nanocrystalline embedded in a block of cementitious material, where the magnetic thread has a composition suitable for not being affected by the alkaline environment of the block of cementitious material and comprises a metal core. Preferably the metal core is a ferromagnetic core.
According to one embodiment, the magnetic micro wire comprises a ferromagnetic core and an insulating glass coating resistant to the alkaline environment of the block of cementitious material, which depending on the cementitious material from which said block is formed is selected from:
- a borosilicate glass coating for high alkali resistance with at least 20-25% Zr, and
- a borosilicate glass coating for moderate alkali resistance with a low alkali content such as the "Pyrex" type 74.5% SiO2, 15% B2O3, 3% Na2O, 2% Al2O3, 1.5% K2O, or " Nonex ”, 73% SiO2, 16.5% B2O3, 6% PbO, 3% Na2O, 1.5% K2O.
According to another embodiment, the magnetic micro wire comprises a ferromagnetic core without the insulating glass coating. In this case, the ferromagnetic core comprises a material selected from Chromium, Zirconium and a combination of them to be resistant to corrosive and oxidizing agents of the block of cementitious material where it is to be embedded.
The present invention also relates to a system of continuous measurement of mechanical resistance in structures of cementitious material based on an electromagnetic induction effect, such that it comprises at least:
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- a sensor of those described above that in the case where the magnetic micro wire comprises glass insulating coating the ferromagnetic core comprises a chemical composition selected from CoFeSiB, FeSiB, FeNiSiB, and FeCoSiB with a Si + B ratio greater than 14% e less than 35%, and Co, Ni and Fe of more than 40%; where the magnetic thread comprises a high and positive magnetostriction in a range from 3e-5 to 4e-5, a magnetic bistability and where the sensor is embedded in the structure of cementitious material;
- an exciter coil;
- a concentric and internal sensor coil to the exciter coil that generates an inverting field inside it;
- an alternating power supply connected to the exciter coil; Y,
- a system for reading and representing the inverter field generated in the sensor coil.
This continuous measurement system based on the effect of electromagnetic induction in turn is divided into two other measurement systems depending on the depth at which the sensor is located, on the one hand a measurement system without connection cables where the exciter coil and the sensor coil is placed externally to the cementitious material structure and on the other hand a measuring system with connection cables where the exciter coil and the sensor coil are previously wrapped around the sensor and embedded together with the sensor in the material structure cementitious
The method of continuous measurement of mechanical resistance in cementitious structures based on the effect of electromagnetic induction comprises:
- generating an alternating current or voltage by means of the alternating power supply that generates a magnetic field in the exciter coil where said magnetic field generates the propagation of a magnetic wall along the magnetic micro wire of the sensor where said magnetic wall generates a narrow pulse of voltage in an inverting field of the sensor coil,
- measure the inverting magnetic field generated in the sensor coil by means of a reading and representation system of the inverting magnetic field,
- establish the mechanical resistance of the cementitious material structure based on the measurement of the inverting magnetic field.
The present invention also relates to another system of continuous measurement of mechanical resistance in structures of cementitious material based on a magnetoinductance effect, such that it comprises at least:
- a sensor of those described above that in the case where the magnetic micro wire comprises insulating glass coating the ferromagnetic core comprises a chemical composition composition selected between CoSiB and CoFeSiB with a Si + B ratio greater than 15% and less than 35% , of Co of more than 40% and Fe less than 6%; where the magnetic thread comprises a low and negative magnetostriction in a range from -1e-7 to 0,
- an alternating power supply connected to the magnetic micro wire,
- an exciter coil wrapped around the sensor,
- a continuous power supply connected to the exciter coil,
- a local field compensation coil wrapped around the sensor and connected to the continuous power supply;
- a voltage reading and representation system as a function of the magnetic field created by the exciter coil,
where the exciter coil and the compensation coil are embedded together with the sensor in the structure of cementitious material.
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The method of continuous measurement of mechanical resistance in cementitious structures based on the effect of magnetoinductance comprises:
- generate an alternating voltage or current that passes through the magnetic wire through the alternating power supply,
- generate a continuous voltage or current that passes through the exciter coil generating a magnetic field,
- generate a continuous voltage or current that passes through the compensation coil to compensate for local fields,
- measure by variations of the voltage at the ends of the magnetic wire as a function of the magnetic field created by the exciter coil, and
- establish the mechanical strength of the cementitious material structure based on the measurement of voltage variations.
Finally, the present invention also relates to a method of fabrication of the described sensor comprising:
• manufacture the amorphous magnetic micro wire using conventional ultrafast cooling and stretching techniques,
• protect the magnetic micro thread by means of a composition suitable to be resistant to the alkaline environment of the block of cementitious material,
• cut the magnetic micro wire into sections and subject it to a thermal treatment selected between electric current and conventional oven to stabilize the internal structure of said magnetic wire, and improve the sensitivity of the magnetic wire to applied mechanical stresses,
• apply a chemical treatment by means of acids to the cut ends of the magnetic thread to obtain uniform and polished ends,
• embed at least the magnetic micro thread in a block of cementitious material; Y
• cure the block of cementitious material by controlling the evolution of its mechanical properties through non-destructive evaluation techniques.
BRIEF DESCRIPTION OF THE FIGURES
To complete the description and in order to help a better understanding of the characteristics of the invention, this descriptive report is attached, as an integral part thereof, a set of drawings where, with an illustrative and non-limiting nature, it has been represented the next:
Figure 1.- Shows a micrograph of a magnetic micro wire using an electron microscope where the ferromagnetic core and the insulating glass coating can be seen.
Figure 2.- Shows the structure of magnetic domains of a micro thread with positive magnetostriction. It has a single magnetic monodomain in the direction of the axis of the magnetic (axial) thread and radial magnetic domains near the surface.
Figure 2a. It shows the different magnetic states of the bistable hysteresis cycle of a magnetic wire with positive magnetostriction. The figure on the left shows the arrows that indicate the direction of the magnetization within each magnetic domain during the different states of the magnetization process corresponding to the stages of the hysteresis cycle.H * represents the minimum magnetic field of inversion, necessary to be able to invert the magnetization.
Figure 3.- Shows the signal induced in the sensor (V2) together with the excitation voltage (V1) as a function of time in arbitrary units (u.a.). The induced signal is due to the propagation of a wall of magnetic domains along the magnetic thread. The magnetic field
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Inversion H * can be easily estimated from the position of an acute peak (maximum) voltage.
Figure 4a.- Shows a distribution of H * field values of a Fe72 5Si125B15 composition before subjecting the magnetic micro wire to thermal and chemical treatment. N is the number of events and H (Oe) the magnetic field investment values. The average value of the fluctuations is H * = 0.83 A / m, the width of the curve is 0.25 Oe.
Figure 4b.- Shows the previous figure after subjecting the magnetic micro wire to the thermal and chemical treatment. It is observed how the induced voltage pulse is now more defined and stable, since the error has been reduced as much as possible in the measure of a certain value of the field H *.
Figure 5a.- It shows an image of the surface imperfections of one end of a magnetic micro wire (in this case the magnetic wire does not have the insulating glass coating) due to an imprecise cut, said image taken by means of an optical microscope. Figure 5b.- Shows an image of one end of a magnetic micro thread (in this case the magnetic micro wire if it has the glass insulating coating) taken by electronic microscope (SEM).
Figure 6a.- Shows a form of realization of a measurement system based on the effect of electromagnetic induction without connection cables. In this case the exciter coil and the sensor coil are outside the structure of cementitious material and at a certain distance from the sensor embedded in the structure of cementitious material.
Figure 6b.- Shows an image of the magnetic micro wire embedded in the block of cementitious material according to the measurement system based on the effect of electromagnetic induction without connection cables.
Figure 6c.- Shows the sensor (block of cementitious material together with the magnetic wire) embedded in a structure of cementitious material according to the measurement system based on the effect of electromagnetic induction without connection cables.
Figure 7a.- Shows an embodiment of a measurement system based on the effect of electromagnetic induction with connection cables.
Figure 7b.- Shows the sensor (block of cementitious material together with the magnetic micro-wire) embedded in a structure of cementitious material according to the measurement system based on the effect of electromagnetic induction with connection cables. The connection cables that are seen belong to the exciter and sensor coil.
Figure 8a.- Shows an electromotive pulse induced in the sensor coil as it is subjected to the block of cementitious material with compressive force. The
dependence on the position of the maximum for two specific measures.
Figure 8b.- Shows an electromotive pulse induced in the sensor coil as it is subjected to the block of cementitious material with compressive force. The
depending on its amplitude depending on the compression force for two specific measures.
Figure 8c.- Shows a schematic drawing of the change in position and amplitude of the induced pulse versus the compression force.
Figure 9.- Shows the structure of magnetic domains of a magnetic micro thread with negative magnetostriction. It fundamentally has circular domains.
Figure 9a.- Schematically shows the characteristic hysteresis cycle of a magnetic micro thread with negative magnetostriction, lying down and without hysteresis.
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Figure 10a.- Shows a form of realization of a measurement system based on the effect of Magnetoinductance (MI) where a continuous field Hdc and another field of a small compensation coil that creates a compensating field, Hc.
Figures 10b1 and 10b2.- Variation of the effective section (and therefore of its impedance), called penetration depth (5), through which the current in the magnetic micro wire passes depending on the application of external fields or forces. As a consequence of the impedance change, the voltage that is what is actually measured varies.
Figure 11.- Shows the magnetoinductance curves at a frequency of 100 KHz as the cementitious material block is subjected to compression forces (KN). The position of the maximum is represented as a function of the applied force.
Below is a list of the different elements represented in the figures that make up the invention:
1. Sensor.
2. Magnetic thread.
3. Ferromagnetic nucleus.
4. Insulating glass coating.
5. Block of cementitious material.
6. Structure of cementitious material.
7. Exciter coil.
8. Sensor coil.
9. Compensation coil.
10. Magnetic field of investment.
11. Connection cables.
12. Function generator.
13. Digital oscilloscope.
14. Resistance.
15. Frequency histogram.
16. Field of excitation.
17. Signal obtained in the magnetic field of investment.
18. Magnetoinductance curves.
19. Electromotive pulse induced in the sensor coil.
20. Structure of magnetic domains of a magnetic micro thread with positive magnetostriction.
21. Bistable hysteresis cycle of a magnetic micro thread with positive magnetostriction.
22. Structure of magnetic domains of a magnetic micro thread with negative magnetostriction.
23. Hysteresis cycle of a magnetic micro thread with negative magnetostriction.
DETAILED DESCRIPTION
The sensor (1) object of the present invention allows to measure the mechanical resistance of any structure made of cementitious material continuously.
Said sensor (1) is embedded directly, as an additional aggregate, in the structure of cementitious material (6) to be studied (which will preferably be concrete), without affecting its structure or the state of tension, so that it can be obtained a continuous monitoring of its state of mechanical stress or internal deformation.
Said compression force sensor (1) comprises a block of cementitious material (5), in which the magnetic thread (2) is embedded, which does not necessarily have to be the same
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cementitious material that forms the structure of cementitious material (6) to be studied, being able to be of cement paste, mortar or concrete.
Said sensor (1) is capable of continuously monitoring the level of compression force to which the cementitious material structure (6) to be studied will be subjected.
The magnetic thread (2) is selected from amorphous and nanocrystalline and has a suitable composition so as not to be affected by the alkaline environment of the block of cementitious material (5). According to a preferred embodiment, the magnetic micro wire (2) comprises a metal core and an insulating glass coating (4). Preferably the metal nucleus is a ferromagnetic nucleus (3) so from now on it will be referred to as a ferromagnetic nucleus (3).
The insulating glass coating (4) is chosen to be resistant to the alkaline environment of the block of cementitious material (5), which depending on the cementitious material from which said block (5) is formed is selected from:
- a borosilicate glass coating for high alkali resistance with at least 20-25% Zr, and
- a borosilicate glass coating for moderate alkali resistance with a low alkali content such as "Pyrex" type 74.5% SiO2, 15% B2O3, 3% Na2O, 2% M2O3, 1.5% K2O, or " Nonex ”, 73% SiO2, 16.5% B2O3, 6% PbO, 3% Na2O, 1.5% K2O.
It is also possible to manufacture magnetic micro wires (2) without the insulating glass coating (4). In this case, the ferromagnetic core (3) comprises a material selected from Chromium, Zirconium and combination of them to be resistant to corrosive and oxidizing agents of the block of cementitious material (5) where it will be embedded.
Corrosive agents are understood as those due to the hydration of the concrete that contains water and can oxidize the magnetic wire (2), or those that can penetrate from the outside as chlorides or sulfates.
The block of cementitious material (5) where the magnetic micro thread (2) is embedded preferably has a cylindrical shape, since it facilitates a calibration of the sensor (1). However, it can have any other geometric shape.
Once the block of cementitious material (5) is manufactured and the magnetic wire (2) is embedded, the sensor (1) is cured under immersion conditions in water with calcium hydroxide for 28 days. During the curing process of the block of cementitious material (5) where the magnetic micro thread (2) is embedded, the evolution of its mechanical properties has been controlled by measuring the ultrasonic speed.
Due to the microscopic diameter of the magnetic wire (2), from 1 to 100 microns, the magnetic wire (2) does not influence the elastic and mechanical properties of the block of cementitious material (5) where it is embedded.
It is important to mention that the range of working forces of the sensor (1) for continuous monitoring of a compression-deformation curve is determined by controlling the following variables of the magnetic thread (2):
i) Its sensitivity to a certain range of mechanical forces can be modified, for a given chemical composition, modifying its structure and magnetostriction on the one hand by means of specific thermal treatments, which allow modifying its magneto-elastic response. They can be summarized in the following:
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Thermal treatment with direct current or in conventional thermal furnace simultaneously with magnetic field or applied mechanical tension. on the other hand, changing the diameter of the ferromagnetic core (3) and the thickness of the glass insulating coating (4) of the magnetic micro wire (2).
ii) Its mechanical compressive strength of the cementitious material block (5) can be modified, varying the manufacturing conditions of the cementitious material block (5), by means of the water / cementitious material ratio, type of cementitious material, and aggregates, additives, as well as the curing conditions of said block of cementitious material (5).
iii) The dimensions of the block of cementitious material (5) can be modified since by modifying the section of the block of cementitious material (5), the mechanical stress affecting the magnetic micro wire (2) is modified.
The manufacture of these magnetic micro wires (2) is carried out by the well-known Taylor-Ulitovski ultrafast cooling technique, where several kilometers of magnetic wire (2) with amorphous structure can be obtained from one gram of alloy. The amorphous structure is achieved thanks to the enormous cooling rate from the molten alloy (1250 ° C) which is of the order of 105-106 ° C / s. The cylindrical shape of the resulting solidified magnetic wire (2) is a consequence of the symmetry of the cooling process on water.
To optimize the response of the sensor (1) thermal treatments have been carried out after the cutting of the magnetic thread (2), since if the magnetic wire (2) is heat treated and subsequently cut, the magnetic domain wall of the magnetic wire (2) destabilizes. Said thermal treatments are applied to the entire magnetic micro wire (2) with electric current or in a conventional oven simultaneously with a magnetic field or applied mechanical tension.
Additionally, chemical treatments have been carried out by means of acids such as HF, HCl and H2SO4 at the cut ends of the magnetic thread (2) after the thermal treatments, to pass from an end with imperfections where the roughnesses are the product of the traces of the tool used for cutting the magnetic thread (2), to a more polished and uniform end.
There are mainly two systems for the continuous measurement of mechanical resistance in the structure of cementitious material (6):
- a first measurement system based on the effect of electromagnetic induction which in turn is divided into two other measurement systems depending on the depth at which the sensor is located (1), on the one hand a measuring system without cables of connection and on the other hand a measuring system with connection cables (11); Y
- a second measurement system based on the effect of magnetoinductance (MI).
These systems are explained below:
Measuring system based on the effect of electromagnetic induction:
The measurement system based on the effect of electromagnetic induction, comprises a power supply that generates an alternating voltage or current in an exciter coil (7) that generates a magnetic field that causes the propagation of a wall of magnetic domain along the Magnetic thread (2) from its end, inducing a narrow voltage pulse as it passes through a sensor coil (8), where the position of the pulse peak
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Narrow voltage depends on the mechanical stresses applied to the magnetic wire (2).
In this case, the magneto-elastic behavior of the magnetic microwires (2) can be modified by choosing a suitable composition, with high magnetostriction so that it is very sensitive to applied mechanical forces, both tension and compression.
For this measurement system, the magnetic thread (2) has specific properties:
- Compositions of CoFeSiB, FeSiB, FeNiSiB, FeCoSiB with a proportion of Si + B greater than 14% and less than 35%, and Co, Ni and Fe of more than 40%. Other elements such as: Mo, Zr, Ge, Cr, Mn, V, Ti, C, Cu, Nb or other metals or metalloids with contents below 7% can be added,
- chemical composition to have high and positive magnetostriction, preferably in the range of 3e-5 to 4e-5 (30-40 ppm, parts per million),
- magnetic bistability,
- Ferromagnetic core geometrical relation (3) / glass insulating coating (4) so as not to be sensitive to the contraction efforts of the cementitious material but to be sensitive to the range of working forces of the sensor,
- The magnetic wire (2), before being embedded in the block of cementitious material (5), has been subjected to:
or a chemical treatment applied to the ends of the magnetic thread (2), by acids such as HF, HCl and H2SO4 to pass from an end with imperfections where the roughnesses are the product of the traces of the tool used for cutting the magnetic thread (2) ), to a more polished and uniform end,
or a thermal treatment for the stabilization of the magnetic wall in the temperature range between 200 and 400 ° C for approximately one hour and the corresponding chemical treatment of the ends. This treatment provides the following advantages:
■ stabilizes the magnetic wall of the micro wire reducing fluctuations in the inverter field, which improves the accuracy of the sensor.
or a thermal treatment with electric current or in a conventional oven, in the temperature range between 200-600 ° C with times that can range from minutes to an hour, depending on each type of sample and treatment, simultaneously with tension force or magnetic field. This heat treatment provides the following advantages:
■ stabilizes the internal structure of the magnetic micro wire (2) over time to improve the stability of the sensor (1),
■ relaxes the internal stresses generated during its manufacture, (at the same time by applying magnetic field or mechanical tension, new efforts are introduced) that allow it to improve its axial magnetization in the direction of the axis of the magnetic thread (2) and therefore fix the its working range so that it has a sensitivity to the mechanical stresses applied in the axial direction of the magnetic thread (2) for that range,
■ for certain values of current and temperature you can even change its amorphous structure to nanocrystalline
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also changing in this way its magnetic behavior, that is to say greater or lesser dependence with the magnetic fields or mechanical tensions applied.
The advantage of the magnetization process in Barkhausen single-jump magnetic micro-wires (2), also called bistable magnetic micro-wires (2), is that a simple induction method can be used for a magnetic field of inversion H * (10). When the external magnetic field exceeds the magnetic reversal field H * (10) caused by an exciter coil (7) fed by a signal, a wall of magnetic domains propagates from its end along the magnetic thread (2) obtaining a electromotive force (fem) induced in a sensor coil (8). Said wall of propagating magnetic domains can be visualized in an oscilloscope as an acute voltage peak, as can be seen in Figure 3. The magnetic field of inversion H * (10) can be easily estimated from the position of that maximum.
The sensor (1) can be influenced by local magnetic fields, or by metal materials around it, such as in reinforced concrete, and since the objective of the sensor (1) is to be embedded in any cementitious material structure to monitor Continuously the efforts, it is necessary to eliminate both the parasitic magnetic fields due to the terrestrial magnetic field and those due to metallic materials around it. Therefore, the measured magnetic field of inversion H * (10) is measured in both directions of the applied magnetic field of excitation. So that a magnetic field of inversion H * + (10) will be measured when the magnetic field of excitation increases and H * - when it decreases. So finally the magnetic field of inversion H * (10), which is used to measure the applied forces (independent of the local field) is proportional to the difference of both components:
„* H + - H *
H = -
23 0
while the local magnetic field or parasite will be given by:
h * = H + + H -
1 local 2
Additionally, the sensor (1), once embedded in a structure of cementitious material, preferably concrete, can be used to measure temperature in extreme cases when the sensor (1) is subject to drastic temperature variations. Finally, if you want to avoid a possible dependence on temperature, you only need to change the measurement conditions of the sensor (1).
It has been shown that at low frequencies of the excitation signal, the sensor (1) has a low sensitivity to mechanical stress and can be used for example as a warning of sudden changes in temperature that may jeopardize the integrity of the material structure cementitious (6). If the frequency of the magnetic field is increased there is an increase in the sensitivity of the sensor (1) to the mechanical tension.
The alloy of the ferromagnetic core (3) of the magnetic wire (2) is carefully chosen so that it has a high magnetostriction constant for measuring the magnetic field of inversion H * (10). Magnetostriction is the property of ferromagnetic materials that deform in the presence of magnetic fields. Here the inverse effect known as the Villari effect is used, which causes variations in magnetic properties (in our case the Inverter Field effects) dependent on the mechanical force applied to them.
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For the measurement of the magnetic field of inversion (10) H *, the magnetic microwires (2) have a particular magnetic structure, exhibit the characteristic of magnetic bistability. And there is an inversion of the magnetization that goes from a stable state of energy to another, by means of a Barkhausen jump. In figure 2, a schematic representation of the monodomain magnetic structure is shown. In Figure 2a, the arrows indicate the direction of the magnetization within each domain during the different states of the magnetization process corresponding to the stages of a completely rectangular hysteresis cycle characteristic of a bistable magnetic micro wire (2) with positive magnetostriction. The change of the magnetization when a magnetic field H is gradually applied in the opposite direction to how it is magnetized in state a) to the field H * where a single Barkhausen jump only occurs from the magnetic wall formed at the end of the magnetic thread ( 2) in state c) until finally obtaining state d). The H * field represents the smallest magnetic field of investment, necessary to be able to invert the magnetization.
In the remainder (a), when a magnetic field is applied in the opposite direction to how the axially magnetized core is in (a), the existing closing domain structures are lengthened towards the center of the sample. (b) In the field of inversion, the wall of one of the two closing domains is irreversibly disengaged and moves towards the opposite end of the sample, resulting in a change in the magnetization (c). Consequently, said Barkhausen jump is a consequence of the release and propagation of a single wall of magnetic domains along the magnetic thread (2). This propagation is defined by a narrow magnetic pulse of a certain duration (figure 3).
However, the value of the inverting magnetic field H * at which the jump in the magnetization occurs presents a small fluctuation when measured repeatedly in the same experimental conditions. To achieve a good sensitivity, a large amplitude, a short duration and that distribution tend to be as narrow as possible are required.
One of the novelties of this measurement system based on the effect of electromagnetic induction is that it has been possible to improve the stabilization of the magnetic domain wall of the magnetic thread (2) thus achieving to optimize the response of the sensor (1) obtaining greater precision in your measurements. In this way, it has been possible to move from the distribution of magnetic field measurements of investment H * (10) of Figure 4a to more stable values of Figure 4b. In this way a more stable peak is achieved that practically does not change position over time.
Figure 5a shows an image of the surface imperfections due to the imprecise cut of one end of the magnetic wire (2) without insulating glass coating (4) taken by an optical microscope, while in figure 5b an image can be seen of the end of a magnetic micro wire (2) with insulating glass coating (4) taken by electron microscopy (SEM).
The methodology of data acquisition and analysis are carried out according to conventional methods where a data acquisition program calculates the maximum value of an induced voltage (in mv) and stores the time in which this maximum has occurred. This routine of recording the position of the maximum is repeated as many times as values of the inverting magnetic field H * (10) are to be measured.
Tests have been carried out with untreated samples, that is, samples to which the aforementioned treatments have not been applied (a statistic has been carried out with two hundred inverter magnetic field data (10)) and they have been compared with samples at that if the above-mentioned treatments have been applied to them and a
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clear substantial decrease in fluctuations and a practically stable inverter magnetic field value around the average value of the approximation curve.
As previously mentioned, depending on the accessibility of the area of the cementitious material structure (6) where the sensor (1) is placed, two different measuring systems will have to be used.
• If the area is accessible and the embedded sensor (1) is in proximity to the surface of the cementitious material structure (6), the measurement system based on the effect of electromagnetic induction without connection cables is used, such and as can be seen in figure 6a, where an exciter coil (7) and a sensor coil (8) are placed external to the cementitious material structure (6) while the sensor (1) is embedded inside said structure of cementitious material (6). The embedded sensor (1) has been previously calibrated in the laboratory by means of force experiments vs. measurement of magnetic parameters. Once the sensor (1) is calibrated, it can be added as an additional aggregate in the fabrication of the cementitious material structure (6) from which the state of forces is to be measured. The sensor (1) must be oriented in the direction you want to measure the stresses.
The exciter coil (7) is fed by a signal, preferably sinusoidal or triangular, in order to apply a linear or gradual external magnetic field that increases with time.
• If the area is not easily accessible, the measurement system based on the effect of electromagnetic induction with connection cables (11) is used, as can be seen in Figure 7a, where the exciter coil (7) and the sensor coil (8) are embedded and wound to the block of cementitious material (5) that has the magnetic micro thread (2) embedded. Connection cables (11) leave the two coils, exciter (7) and sensor (8), as shown in Figure 7b.
The connection cables (11) are thin coaxial cables and are preferably covered with polytetrafluoroethylene (PTFE) so that they are not damaged by being embedded in the block of cementitious material (5).
Measurement system based on the effect of magnetoinductance (MI):
Next, the measurement system based on the effect of magnetoinductance (MI) is explained (Figure 10a), where an alternating power supply is observed to pass a low frequency alternating current (100 Hz-200 KHz) through of the magnetic micro wire (2) of a small amplitude comprised between 50 mV and 1V and a continuous power supply is also observed to generate a continuous voltage or intensity through the exciter coil (7) concentrically wound around the material block cementitious (5) containing the magnetic micro wire (2) by thin coaxial cables protected by PTFE. There is also a compensation coil (9) wound on the block of cementitious material (5) to compensate for local fields that may affect the sensitivity of the sensor (1).
For this measurement system, the magnetic thread (2) has specific properties:
- mainly compositions of CoSiB, CoFeSiB with a proportion of Si + B greater than 15% and less than 35%, and Co of more than 40% and Fe not exceeding 6%. In the same way it can comprise other metals or metalloids such as, Mo, Zr, Ge, Cr, Mn, V, Ti, C not exceeding 7%,
- It can also comprise FeSiB, FeNiSiB compositions with a Si + B ratio greater than 14% and less than 35%, and of, Ni and Fe plus
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of 40%. However, it must include other metals or metalloids, with contents not exceeding 7% such as Hf, Nb, Cu that allow its nano-crystallization under thermal treatment with electric current or conventional furnace to be able to obtain a magnetostriction low enough so that it can be measured by this measurement system,
- chemical composition to have low and negative magnetostriction, in the range - 1e-7 to 0,
- circular domain structure, to be easily magnetized by an electric current,
- Ferromagnetic core geometrical relation (3) / glass insulating coating (4) so as not to be sensitive to the contraction efforts of the cement but to be sensitive in a desired range of forces,
- The magnetic wire (2), before being embedded in the block of cementitious material (5), has been subjected to:
or a thermal treatment with electric current or in a conventional oven, in the temperature range between 200-600 ° C with times that can range from minutes to an hour, depending on each type of sample and treatment, simultaneously with tension force or magnetic field. This heat treatment provides the following advantages:
■ stabilizes the internal structure of the magnetic micro wire (2) over time to improve the stability of the sensor (1),
■ relaxes the internal stresses generated during its manufacture, (at the same time by applying magnetic field or mechanical tension, new efforts are introduced) that allow to improve the circular magnetization of the magnetic thread (2) and therefore set its working range so that it has a sensitivity to the mechanical stresses applied in the axial direction of the magnetic thread (2) for that range,
■ for certain values of current and temperature, its amorphous structure can even be changed to nanocrystalline, also changing its magnetostatic behavior, that is, greater or lesser dependence on the magnetic fields or mechanical stresses applied. In the case of the aforementioned compositions with a value of Fe, Ni, Co greater than 40%, it is necessary to nanocrystallize them so that they can be measured by this measurement system.
Magnetoinductance unlike magnetoresistance, which refers to the variation of the electrical resistance of a material when it is subjected to an external magnetic field, consists of the variation of the complex impedance, Z = R + jwL that occurs when through the Magnetic micro wire (2) is passed an alternating electric current in the presence of an external magnetic field. R is the resistive or real part of the impedance and wL the imaginary part or inductive reactance, where w is the angular frequency of the current and L is the inductance of the magnetic wire (2).
The measurement of the effect of magnetoimpedance (MI) lies in the variations in the depth of penetration of the electromagnetic field as a function of the circular permeability of the magnetic wire (2) known as the film effect.
For this measurement system, magnetic micro wires (2) with low and negative magnetostriction are chosen so that an intense variation of the circular magnetization can be induced by passing an electric current.
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Figure 9 shows that the easy magnetization axis is circular, which determines a circular configuration of the domain structure.
The penetration depth is given by:
8
P

where p is the resistivity of the magnetic micro wire (2), p is its circular permeability and f is the frequency of the alternating magnetic field that passes through said material. Normally, the current is mainly concentrated near the surface of the magnetic wire (2) without the application of any external force or field (see Fig. 10b1) because induced currents are generated that oppose the variation of the alternating current. The application of an HDC field or the applied mechanical force F decreases the circular permeability p of the magnetic micro wire (2), so according to the equation, the penetration depth of the current increases from 8i to 8f, now passing through a larger section of the magnetic micro thread (2) (see Fig. 10-2). Since the impedance Z of the material is inversely proportional to the area of the area of the material through which current flows, the impedance decreases. Changes in the impedance value result in changes in the Vout voltage, which is what is really measured. The maximum impedance is obtained when the circular permeability is maximum. Depending on the magnetic anisotropla of the magnetic micro-wire (2), axial or circular, the magnetoimpedance curve will have a single peak or two, respectively. From the variation of the position of the peak or its amplitude, we obtain the dependence with the applied compression force. In our case we measure at relatively low frequencies, the effect is called magneto-inductance, where the dependence with the magnetic field comes mainly from the inductive term, jwL, where L is the inductance of the magnetic micro wire (2).
This effect was measured using the four-pointed method; two contacts to pass an electric current to the magnetic micro wire (2), and those same contacts to detect the variations in voltage that it experiences depending on the magnetic field and mechanical force applied.
In this measurement system based on the effect of magnetoinductance, the exciter coil (7) is wrapped around the sensor (1) (magnetic micro wire (2) embedded in the block of cementitious material (5)), where connection cables leave the Magnetic thread (2), as shown in Figure 10a. The connection cables are thin coaxial cables and are preferably covered with polytetrafluoroethylene (PTFE) so that they are not damaged by being embedded in the block of cementitious material (5).
There is also a small compensation coil (9) wound on the block of cementitious material (5) where the magnetic thread (2) is embedded, which creates a compensation field Hc, see Fig. 10a, to compensate in this way for a field local magnet if present. The existence of a local magnetic field can affect the impedance of the magnetic micro wire (2), thus affecting the sensitivity of the sensor (1).
The greatest difficulty of this measuring system based on the effect of magnetoinductance lies in the connection of the connection cables with the magnetic wire (2). The connection of said cables is carried out as follows:
S In the event that the magnetic micro wire (2) has the glass insulating coating (4), the ends of the magnetic micro wire (2) must be chemically treated with acid at a specific time to remove said glass insulating coating (4) without attacking the ferromagnetic nucleus too much (3); If, on the other hand, there is no such insulating glass coating (4), the ends will be soldered directly by electric arc.
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S Weld the ends by electric arc, that is, by means of a continuous electric current, where an electric arc is formed between the ferromagnetic core (3) to be welded and an electrode used (in our case copper), producing the fusion of the surrounding copper to the stripped end of the magnetic thread (2).
S Protect the ends of the magnetic thread (2) by means of a special epoxy that gives it some mechanical resistance, and protection against the cementitious environment and humidity.
Both measurement systems are easily implemented electronically, which would allow it to use systems based on wireless sensor networks or RFID technology to monitor the properties of the cementitious material structure (6) under study.
The present invention should not be limited to the embodiment described here. Other configurations may be made by those skilled in the art in view of the present description. Accordingly, the scope of the invention is defined by the following claims.
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1. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of cementitious material (6) characterized in that it comprises: at least one magnetic micro-wire (2) selected between amorphous and nanocrystalline embedded in a block of cementitious material (5) , where the magnetic micro wire (2) is resistant to the alkaline environment of the block of cementitious material (5) and comprises a metal core (3).
2. Sensor (1) embedded for the continuous measurement of mechanical resistance in cementitious structures (6), according to claim 1, characterized in that the structure of cementitious material (6) is concrete.
3. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of cementitious material (6), according to any one of the preceding claims, characterized in that the metal core (3) is ferromagnetic.
4. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of
cementitious material (6), according to claim 3, characterized in that the core
Ferromagnetic (3) comprises a material selected from Chromium, Zirconium and combination thereof to be resistant to oxidizing agents of the block of cementitious material (5).
5. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of
cementitious material (6), according to claim 3, characterized in that the core
Ferromagnetic (3) comprises an insulating glass coating (4) to be resistant to the environment of the block of cementitious material (5).
6. Sensor (1) embedded for the continuous measurement of mechanical resistance in cementitious structures (6), according to claim 5, characterized in that the insulating glass coating (4) is a borosilicate glass coating.
7. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of cementitious material (6), according to claim 6, characterized in that the borosilicate glass coating comprises a composition selected from 74.5% SiO2, 15% B2O3, 3% Na2O, 2% M2O3, 1.5% K2O, and 73% SiO2, 16.5% B2O3, 6% PbO, 3% Na2O, 1.5% K2O.
8. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of cementitious material (6), according to claim 6, characterized in that the borosilicate glass coating comprises a composition of at least between 20-25% of Zr.
9. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of
cementitious material (6), according to claim 5, characterized in that the core
Ferromagnetic (3) comprises a chemical composition selected from CoFeSiB, FeSiB, FeNiSiB, and FeCoSiB with a proportion of Si + B greater than 14% and less than 35%, and Co, Ni and Fe of more than 40%.
10. Sensor (1) embedded for the continuous measurement of mechanical resistance in structures of
cementitious material (6), according to claim 5, characterized in that the core
Ferromagnetic (3) comprises a chemical composition selected from CoSiB and CoFeSiB with a Si + B ratio greater than 15% and less than 35%, Co of more than 40% and Fe less than 6%.
11. Continuous measurement system of mechanical resistance in structures of cementitious material (6) based on an electromagnetic induction effect, characterized in that it comprises at least:

权利要求:
Claims (7)
[1]
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- a sensor (1) described in any one of claims 1 to 9, wherein the magnetic micro wire (2) comprises a high and positive magnetostriction in a range from 3e-5 to 4e-5, a magnetic bistability and where the sensor ( 1) is embedded in the structure of cementitious material (6);
- an exciter coil (7);
- a concentric and internal sensor coil (8) to the exciter coil (7) that generates an inverting field therein;
- an alternating power supply connected to the exciter coil (7); Y,
- a system for reading and representing the inverter field generated in the sensor coil (8).
[12]
12. Continuous measurement system of mechanical resistance in structures of cementitious material (6) based on the effect of electromagnetic induction, according to claim 11, characterized in that the exciter coil (7) and the sensor coil (8) are externally placed the structure of cementitious material (6).
[13]
13. Continuous measurement system of mechanical resistance in structures of cementitious material (6) based on the effect of electromagnetic induction according to claim 11, characterized in that the exciter coil (7) and the sensor coil (8) are previously wound around the sensor (1) and embedded together with the sensor (1) in the structure of cementitious material (6).
[14]
14. System of continuous measurement of mechanical resistance in structures of cementitious material (6) based on the effect of magnetoinductance, characterized in that it comprises at least:
- a sensor (1) described in any one of claims 1 to 8 and 10, wherein the magnetic micro wire (2) comprises a low and negative magnetostriction in a range from -1e-7 to 0,
- an alternating power supply connected to the magnetic micro wire (2),
- an exciter coil (7) wrapped around the sensor (1),
- a continuous power supply connected to the exciter coil (7),
- a compensation coil (9) of local fields wrapped around the sensor (1) and connected to the continuous power supply;
- a voltage reading and representation system as a function of the magnetic field created by the exciter coil (7),
where the exciter coil (7) and the compensation coil (9) are embedded together with the sensor (1) in the structure of cementitious material (6).
[15]
15. Method of continuous measurement of mechanical resistance in structures of cementitious material (6) based on the effect of electromagnetic induction that makes use of the measurement system defined in claims 11 to 13, characterized in that it comprises:
- generating an alternating current or voltage by means of the alternating power supply that generates a magnetic field in the exciter coil (7) where said magnetic field generates the propagation of a magnetic wall along the magnetic micro wire (2) of the sensor (1) where said magnetic wall generates a narrow voltage pulse in an inverting field of the sensor coil (8),
- measure the inverting magnetic field (10) generated in the sensor coil (8) by means of a reading and representation system of the inverting magnetic field (10),
- establish the mechanical strength of the structure of cementitious material (6) based on the measurement of the inverting magnetic field (10).
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[16]
16. Method of continuous measurement of mechanical resistance in structures of cementitious material (6) based on the effect of magnetoinductance that makes use of the measurement system defined in claim 14, characterized in that it comprises:
- generate an alternating voltage or current that passes through the magnetic wire (2) by means of the alternating power supply,
- generate a voltage or direct current that passes through the exciter coil (7) generating a magnetic field,
- generate a continuous voltage or current that passes through the compensation coil (9) to compensate for local fields,
- measure by variations of the voltage at the ends of the magnetic micro wire (2) as a function of the magnetic field created by the exciter coil (7), and
- establish the mechanical resistance of the structure of cementitious material (6) based on the measurement of the voltage variations.
[17]
17. Method of fabrication of the embedded sensor (1) defined in any one of claims 1 to 10, characterized in that it comprises:
• manufacture the amorphous magnetic wire (2) using conventional ultra-fast cooling and stretching techniques,
• protect the magnetic micro thread (2) by means of a composition suitable to be resistant to the alkaline environment of the block of cementitious material (5),
• cut the magnetic micro wire (2) into sections and subject it to a thermal treatment selected from electric current and with a conventional oven to stabilize the internal structure of said magnetic wire (2), and improve the sensitivity of the magnetic wire (2) to stress applied mechanics,
• apply a chemical treatment by means of acids to the cut ends of the magnetic thread (2) to obtain uniform and polished ends,
• embed at least the magnetic micro thread (2) in a block of cementitious material (5); Y
• cure the block of cementitious material (5) by controlling the evolution of its mechanical properties through non-destructive evaluation techniques.
image 1

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同族专利:

公开号 | 公开日

DOP2016000309A|2017-02-15|

ES2802498T3|2021-01-19|

EP3150998A1|2017-04-05|

EP3150998B1|2020-01-08|

WO2015181422A1|2015-12-03|

EP3150998A4|2018-02-14|

ES2555542B1|2016-10-19|

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